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1


What is the primary role of transition metal ion catalysts in the catalytic ozonation process for nanoplastic removal?

To decrease the reaction time without enhancing removal efficiency

because transition metal can easily give and accept electrons this would enchancing the chance of chemical reaction to occurs

chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms

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2


According to the article, what was the observed effect of using Co2+ at 1 mM on the mineralization rate of polystyrene nanoplastics during ozonation?

Increased mineralization rate by 70%

transition metal can easily give and accept electrons this would enchancing the chance of chemical reaction to occurs thats why the rate is changed

the highest PSNPs ozonation performance was achieved, decreasing the turbidity up to 65 % and achieving 70 % of mineralization in the same ozonation time.

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3


In the context of nanoplastics removal, what does the scavenger experiment with methanol demonstrate about the catalytic ozonation process?

Methanol acts as an alternative catalyst

ozonation at disinfection doses reduced the particle size of PSNPs ,the catalytic process demonstrated greater efficacy in the total removal of PSNPs.

the catalytic process demonstrated greater efficacy in the total removal of PSNPs.

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4


If the initial concentration of nanoplastics is 20 mg/L and the catalytic ozonation achieves a 70% mineralization rate, what is the concentration of remaining nanoplastics?

6 mg/L

70/100 x20 = 14 20-14 = 6

70/100 x20 = 14 20-14 = 6 The question asks for remaing nanoplastic

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5


Given an ozone flow rate of 0.5 NL/min and an ozonation time of 120 minutes, how much ozone (in grams) has been used if the ozone concentration is 10 mg/NL?

600 grams

v=s/t 0.5x120 s=60 c=m/v 10x60=600

in this point i give s as a v (volume) accoding to concentration formula after my calculation, i got the answer m=600

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6


If reducing the turbidity of water by catalytic ozonation with Co2+ from 100 NTU to 35 NTU represents a 65% reduction, what was the original turbidity?

100 NTU

because it reduces by 65% and 65% of 100 is 65 100-65 = 35 then the original turbidity will be 100

because it reduce by 65% and 65% of 100 is 65 100-65 = 35 then the original turbidity will be 100

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7


What is a major benefit of catalytic ozonation over single ozonation in water treatment?

It provides higher mineralization rates

according to the experiment the catalytic ozonation has higher rate of mineralization than single ozonation

The single ozonation of PSNPs, in the absence of catalyst, led to low turbidity reduction (33 %) and low mineralization rate (16 %) even after 2 h reaction time. Nevertheless, the rapid size reduction of PSNPs by >99 % in less than 5 min of ozonation (TOD: 30 mg L−1) was confirmed. This fact could imply a new issue under the ozone disinfection conditions by the formation of smaller-size particles. However, in the presence of Co2+ (1 mM), the highest PSNPs ozonation performance was achieved, decreasing the turbidity up to 65 % and achieving 70 %

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8


Which of the following is NOT a transition metal ion used as a catalyst in the study?

Ca2+

ca2+ is not a transition metal

because ca2+ is located at the left side of the table that means ca2+ is a alkane earth metal

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9


What environmental issue does the removal of nanoplastics address?

Reduction of water pollution

because PSNPs cause the water to be contaminated

the PNSPs molecule is very small even after the single ozonation so it can easily cause water to contaminate

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10


What analytical technique is NOT mentioned as used for monitoring the degradation of nanoplastics?

Mass Spectrometry

because the GPC is use for finding molecule weight

because the GPC is use for finding molecule weight so Mass Spectrometry is not neccessary

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11


What effect does the melt fiber spinning system have on the crystallinity of PET fibers?

It decreases the crystallinity to less than 10%.

test with a one time use water bottle extruded,drawn and spooled as thin fibers that cool by passive heat dissipation rapidly enough to quench the polymer to low crystallinity (<10%)

https://www.sciencedirect.com/science/article/pii/S2666821124000425

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12


What role does the spooling speed play in the fiber spinning system described in the article?

Higher spooling speeds lead to lower crystallinity and smaller fiber diameters.

according to article it said that" we estimate the fiber spinning also increases the feedstock surface-area-to-volume ratio by up to 15-fold"

we estimate the fiber spinning also increases the feedstock surface-area-to-volume ratio by up to 15-fold

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13


According to the article, what was the impact of using the LCC-ICCG enzyme on PET depolymerization?

It significantly increased the monomer release from PET.

because LCC-ICCG enzyme use as a seperator so it increase the monomer release from PET.

This enzyme is an engineered version of the leaf branch compost cutinase

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14


If the initial mass of PET before enzymatic treatment in a bioreactor was 500 grams and 96.9% mass was lost due to depolymerization, what is the final mass of PET?

484.5 grams

96.9/100 x 500 = 484.5 ans 484.5 grams

96.9/100 x 500 = 484.5

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15


Considering the average crystallinity of PET fibers after treatment is 9.7%, what would be the crystallinity if the process conditions were unaltered but the drop distance doubled?

19.4%

double distance means double crystallinity

Small scale PET depolymerization testing was performed at 10 mL volumes in test tubes. Unless otherwise noted, all reactions were performed by incubating select PET melt spin fibers (19 g/L buffer) with purified LCC-ICCG enzyme (1 mg/g PET) in 100 mM potassium phosphate buffer, pH 8 at 65 °C with agitation. All melt spin fibers were spooled from an 18″ drop, except the 0 rpm condition, which was from a 9″ drop. Bench reactions were performed in triplicate in 50 mL centrifuge tubes and agitated at an angle (∼45° tilt) at 200 rpm

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16


If the surface area to volume ratio of PET increased 15-fold due to processing, and the initial ratio was 0.1 mm²/mm³, what is the new ratio?

1.5 mm²/mm³

0.1x15

0.1x15

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17


What is a major advantage of the melt fiber spinning system over traditional recycling methods?

Reduces the need for high capital investment

according to the article , In conclusion, this pre-processing approach was demonstrated to be effective for real-world PET products and has advantages over other approaches in its low capital cost requirement,

In conclusion, this pre-processing approach was demonstrated to be effective for real-world PET products and has advantages over other approaches in its low capital cost requirement,

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18


What does the term 'amorphous content' refer to in the context of PET recycling?

The unstructured, non-crystalline state of PET

amorphus is about the structured of the object

https://www.sciencedirect.com/science/article/pii/S2666821124000425

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19


What is the primary benefit of reducing the crystallinity of PET in recycling processes?

It increases the mechanical strength of the recycled PET.

so after the recycling process PET can still be use

https://www.sciencedirect.com/science/article/pii/S2666821124000425

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20


Which measurement technique was used to assess the polymer spectra to confirm the presence of PET?

Fourier Transform Infrared Spectroscopy

To see polymer

https://www.sciencedirect.com/science/article/pii/S2666821124000425

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ผลคะแนน 94.6 เต็ม 140

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